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QD-2: A Novel Open-Framework Aluminoborate with Intersecting Three-Dimensional Helical Channels

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https://figshare.com/articles/dataset/QD_2_A_Novel_Open_Framework_Aluminoborate_with_Intersecting_Three_Dimensional_Helical_Channels/2933671
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资源简介:
A novel open-framework aluminoborate, [CH3NH2(CH2)3NH3][AlB5O10] (QD-2), has been synthesized under hydrothermal conditions and characterized by IR, elemental analysis, thermogravimetric analysis, and powder and single-crystal X-ray diffractions. The compound crystallizes in the orthorhombic system, space group P212121 (No. 19), a = 9.4352(4) Å, b = 10.2972(2) Å, c = 13.7511(5) Å, V = 1336.0(8) Å3, and Z = 4. Its structure consists of AlO4 tetrahedra and B5O10 clusters, which are interconnected to form the first example of a three-dimensional aluminoborate with intersecting helical channels.
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2008-06-16
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