Syntheses of Chloroisosulochrin and Isosulochrin and Biomimetic Elaboration to Maldoxin, Maldoxone, Dihydromaldoxin, and Dechlorodihydromaldoxin
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https://figshare.com/articles/dataset/Syntheses_of_Chloroisosulochrin_and_Isosulochrin_and_Biomimetic_Elaboration_to_Maldoxin_Maldoxone_Dihydromaldoxin_and_Dechlorodihydromaldoxin/2622232
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资源简介：
An efficient synthesis of chloroisosulochrin was accomplished using a novel ortho-selective chlorination of a phenol with sulfuryl chloride and 2,2,6,6-tetramethylpiperidine as the key step. Further elaboration by a biomimetic route converted chloroisosulochrin to dihydromaldoxin, maldoxone (lactone formed by dehydration of dihydromaldoxin), and maldoxin and isosulochrin to dechlorodihydromaldoxin and dechloromaldoxin.
创建时间：
2016-02-23
