A Pauson−Khand and Ring-Expansion Approach to the Aquariane Ring System
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https://figshare.com/articles/dataset/A_Pauson_Khand_and_Ring_Expansion_Approach_to_the_Aquariane_Ring_System/3069808
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资源简介：
The carbocyclic ring system of the aquariolide diterpenes has been synthesized by two routes involving a diastereoselective Pauson−Khand
reaction and subsequent ring expansion. In one route, a tetracyclic enone was elaborated to generate the nine-membered ring by Grob
fragmentation. In the second approach, a spirocyclic tricycle underwent a facile anionic oxy-Cope rearrangement to complete the synthesis
of the desired ring system.
创建时间：
2016-03-01
