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Synthesis and Characterization of α‑Diimine Complexes of Group 13 Metals and Their Catalytic Activity toward the Epoxidation of Alkenes

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NIAID Data Ecosystem2026-03-08 收录
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https://figshare.com/articles/dataset/Synthesis_and_Characterization_of_Diimine_Complexes_of_Group_13_Metals_and_Their_Catalytic_Activity_toward_the_Epoxidation_of_Alkenes/2145115
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Complexes of group 13 metal (Al, Ga, In) ions with neutral α-diimine ligands have been prepared and characterized. The AlIII and GaIII [M­(α-diimine)2Cl2]­[MCl4] complexes catalyze the epoxidation of alkenes by peracetic acid under ambient conditions. The two complexes display nearly identical reactivity, demonstrating that inexpensive and highly abundant aluminum is a viable catalytic metal for these reactions.
创建时间:
2016-02-13
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