Synthesis and Characterization of α‑Diimine Complexes of Group 13 Metals and Their Catalytic Activity toward the Epoxidation of Alkenes
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https://figshare.com/articles/dataset/Synthesis_and_Characterization_of_Diimine_Complexes_of_Group_13_Metals_and_Their_Catalytic_Activity_toward_the_Epoxidation_of_Alkenes/2145115
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资源简介:
Complexes
of group 13 metal (Al, Ga, In) ions with neutral α-diimine ligands
have been prepared and characterized. The AlIII and GaIII [M(α-diimine)2Cl2][MCl4] complexes catalyze the epoxidation of alkenes by peracetic
acid under ambient conditions. The two complexes display nearly identical
reactivity, demonstrating that inexpensive and highly abundant aluminum
is a viable catalytic metal for these reactions.
创建时间:
2016-02-13



