Palladium-Catalyzed Cyclization of a Pyryne Precursor to Higher Pyrenylenes [Data]
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By palladium-catalyzed oligomerization reactions of pyrene-based o-trimethylsilyl triflates, larger cyclic pyrenylenes were formed with up to 10-membered rings as has been unambiguously characterized by SCXRD. Furthermore, the underlying reaction mechanism has been studied by quantum chemical calculations.
创建时间:
2023-01-01



