C−H Activation as a Strategic Reaction: Enantioselective Synthesis of 4-Substituted Indoles
收藏NIAID Data Ecosystem2026-03-06 收录
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A method is described for the asymmetric synthesis of 4-substituted indoles from the Rh2(S-DOSP)4-catalyzed decomposition of vinyldiazoacetates in the presence of N-Boc-4-acetoxy-6,7-dihydroindole. The reaction proceeds via a combined C−H activation/Cope rearrangement-elimination mechanism resulting in good yields and very high asymmetric induction.
创建时间：
2016-05-12
