A New Monomeric Saturated N-Heterocyclic Silylene as a Racemic Mixture
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https://figshare.com/articles/dataset/A_New_Monomeric_Saturated_N_Heterocyclic_Silylene_as_a_Racemic_Mixture/3068200
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资源简介:
A new stable silylene, rac-N,N‘-di-tert-butylethylene-4,5-dimethyl-1,3-diaza-2-silacyclopentan-2-ylide, has been made
by reaction of the corresponding dibromide with KC8. Unlike
the analogous silylene lacking the two methyl groups, which
tetramerizes in concentrated solution or as a solid, the new
silylene shows no tendency to oligomerize; instead, it persists
as a stable colorless liquid.
创建时间:
2016-03-01



