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Effect of local structure on negative thermal expansion

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ESRF Portal2027-01-01 更新2026-04-23 收录
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https://doi.esrf.fr/10.15151/ESRF-ES-1719224265
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We have recently identified a transition from positive to zero to negative thermal expansion by fluoride doping NbO2F. Anionic control over thermal expansion is a novel approach and the mechanism through which it operates is currently not fully understood. Analysis of local structure through the x-ray pair distribution function (PDF) at different temperatures will allow us to separate the influences of anion order from dynamic distortions, and would help to develop this new field of anionic control of thermal expansion.
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University of Edinburgh,School of Chemistry,Joseph Black Building,David Brewster Road,EH9 3FJ EDINBURGH,EH9 3FJ,EDINBURGH,UNITED KINGDOM
创建时间:
2027-01-01
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