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From Discrete Linear Zn<i><sup>t</sup></i><sup></sup>Bu<sub>2</sub> Molecules to 1D Coordination Polymers and 2D Fabrics

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NIAID Data Ecosystem2026-03-06 收录
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We have authenticated the molecular and crystal structure of ZntBu2 and constructed the unprecedented 2D fabric structure using the tert-butylzinc molecules and 1,2-bis(4-pyridyl)ethane as building blocks. The X-ray crystal structure analysis revealed that the inorganic−organic polymeric chains were weaving to form the fabric structure by the concerted C−H···π interactions involving the pyridine rings. Subtle factors governing self-assembly processes leading to a fabric structure are discussed.

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2007-03-21
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