Synthetic Access to All Four Stereoisomers of Oxetin
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https://figshare.com/articles/dataset/Synthetic_Access_to_All_Four_Stereoisomers_of_Oxetin/3978288
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资源简介:
A short
synthesis of all four stereoisomers of 3-amino-2-oxetanecarboxylic
acid (oxetin) is described. The oxetane core is built using a Paternò–Büchi
photochemical [2 + 2] cycloaddition; from the key intermediates, complementary
resolution protocols provide access to enantiomerically pure oxetin
and epi-oxetin on gram-scale.
创建时间:
2016-10-17



