The First Mixed-Valent Antimony(III/V) Oxo Clusters (2,6-Mes2C6H3Sb)2(ClSb)4O8 and (2,6-Mes2C6H3Sb)4(ClSb)4(HOSb)2O14†
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The kinetically controlled base hydrolysis of the sterically encumbered arylantimony dichloride 2,6-Mes2C6H3SbCl2 (1) under aerobic conditions afforded [2,6-Mes2C6H3(Cl)SbIII]2O (2) and the mixed-valent clusters (2,6-Mes2C6H3SbV)2(ClSbIII)4O8 (3) and (2,6-Mes2C6H3SbV)4(ClSbIII)4(HOSbIII)2O14 (4), whose molecular structures are dominated by hypervalent and secondary bonding.
创建时间:
2007-07-16




