Synthesis and Characterization of Two New Mn(II) Coordination Polymers Containing Different Metal-Carboxylate Chain Motifs
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https://tandf.figshare.com/articles/dataset/Synthesis_and_Characterization_of_Two_New_Mn_II_Coordination_Polymers_Containing_Different_Metal_Carboxylate_Chain_Motifs/1250962/2
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Two Mn(II) coordination polymers, formulated as [Mn(Hhtpa)<sub>2</sub>(bpa)<sub>2</sub>(H<sub>2</sub>O)]<i><sub>n</sub></i> (1) and {[Mn(htpa)(H<sub>2</sub>O)]·H<sub>2</sub>O}<i><sub>n</sub></i> (2) (htpa = 4-carboxyphenylacetate, bpa = 1,2-di(4-pyridyl)-ethane), have been synthesized by the hydrothermal reaction and characterized by single-crystal X-ray diffraction, elemental analysis, IR, and thermo-gravimetric analyses (TGA). The structures of both compounds are based on different Mn(II)-carboxylate chain motifs. Complex 1 is a one-dimensional coordination polymer featuring <i>μ</i><sub>2</sub>-carboxyl bridged MnO<sub>4</sub>N<sub>2</sub> octahedra. Complex 2 contains Mn-O inorganic chains, featuring <i>μ</i><sub>2</sub>-O bridged MnO<sub>6</sub> octahedra, which are interconnected further by interchain htpa ligands to form a two-dimensional coordination polymer.
提供机构：
Taylor & Francis
创建时间：
2016-01-19
