Hydroxyphosphinylation Reaction of 3‑Cyclopropylideneprop-2-en-1-ones via C–P σ‑Bond Cleavage
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https://figshare.com/articles/dataset/Hydroxyphosphinylation_Reaction_of_3_Cyclopropylideneprop_2_en_1_ones_via_C_P_Bond_Cleavage/2403052
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资源简介：
An
unexpected hydroxyphosphinylation of 3-cyclopropylideneprop-2-en-1-ones
with phosphines has been observed. This method provides a unique regio-
and stereoselective synthesis of highly functionalized 1-dialkylphinyl-3-oxo-(1Z)-alkenyl cyclopropanols with important potentials. The
reaction displays an unusual mechanistic featurea highly selective
cleavage of C–P σ bonds in phosphines.
创建时间：
2016-02-19
