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Encapsulation of Halides within the Cavity of a Pentafluorophenyl-Substituted Tripodal Amine Receptor

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https://figshare.com/articles/dataset/Encapsulation_of_Halides_within_the_Cavity_of_a_Pentafluorophenyl_Substituted_Tripodal_Amine_Receptor/3002506
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资源简介:
Pentafluorophenyl-substituted tripodal amine L, tris[[(2,3,4,5,6-pentafluorobenzyl)amino]ethyl]amine, is becoming a potential receptor for encapsulation of Cl- and Br- within the pseudo-C3-symmetric tris(2-aminoethyl)amine (L1) cavity upon protonation of the secondary amines. 1H NMR titration results indicate that [H3L]3+ binds with Cl- and Br- strongly compared to the [H3L2]3+ receptor, where L2 is N,N‘,N‘ ‘-tris[(2-benzylamino)ethyl]amine.
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2016-07-05
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