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Crystal Growth and Single-Crystal Structures of <i>RE</i>RhO<sub>3</sub> (<i>RE</i> = La, Pr, Nd, Sm, Eu, Tb) Orthorhodites from a K<sub>2</sub>CO<sub>3</sub> Flux

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Single crystals of LaRhO3, PrRhO3, NdRhO3, SmRhO3, EuRhO3, and TbRhO3 have been grown for the first time using a K2CO3 flux. All the compounds were found to crystallize in the orthorhombic space group Pbnm (No. 62) and adopt the GdFeO3 distorted perovskite structure type. Transition toward a pseudo-cubic cell is noted as the rare earth cation size increases.

创建时间:
2016-03-01
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