A Rh<sup>II</sup>−Au<sup>II</sup> Bimetallic Core with a Direct Metal−Metal Bond
收藏NIAID Data Ecosystem2026-03-06 收录
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The d8···d10 heterobimetallic RhIAuI(tfepma)2(CNtBu)2Cl2 (1) complex (tfepma = bis[bis(trifluoroethoxy)phosphino]methylamine) is oxidized by KAuIIICl4 to give the first structurally characterized d7−d9 RhII−AuII singly bonded metal complex [RhIIAuII(tfepma)2(CNtBu)2Cl3]+[AuICl2]- (2). Complex 2 undergoes a thermal intermetal redox reaction to generate fac-RhIII(tfepma)(CNtBu)Cl3 (3) and Au2I,I(tfepma)2Cl2 (4).
创建时间：
2016-02-29
