Room-Temperature Characterization of a Mixed-Valent μ‑Hydroxodicopper(II,III) Complex
收藏Figshare2016-08-31 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Room-Temperature_Characterization_of_a_Mixed-Valent_Hydroxodicopper_II_III_Complex/3573969
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Bis(μ-hydroxo)dicopper(II,II) bearing a naphthyridine-based ligand has been synthesized and characterized in the solid state and solution. Cyclic voltammetry at room temperature displays a reversible redox system that corresponds to the monoelectronic oxidation of the complex. Spectroscopic and time-resolved spectroelectrochemical data coupled to theoretical results support the formation of a charge-localized mixed-valent CuII,III2 species.
创建时间：
2016-08-31
