Order parameter of dual-frequency nematic liquid crystals measured over a wide range of thicknesses

Basic physical properties of liquid crystals strongly depend on the orientational order parameter. Given a fundamental importance of this parameter, it was measured for a variety of liquid crystals by means of various experimental techniques. At the same time, the reported results were limited to a relatively narrow range of thicknesses of the studied liquid crystal cells (typically, within a 1–20 µm interval). This paper presents the values of the orientational order parameter of dual-frequency nematic liquid crystals measured over a wide range of thicknesses (from 5 to 200 µm). The non-monotonous dependence of the order parameter <i>S</i> on the cell thickness obtained for relatively thin layers (&lt; 60 µm) of dual-frequency nematics is followed by a rapid monotonous decay of <i>S</i> for thicker (60–200 µm) liquid crystal samples. The obtained results are important for the development of emerging, non-display, applications of liquid crystals utilising thick cells and fast switching materials such as dual-frequency nematics. In particular, they provide a basis for understanding recently discovered two regimes of electro-optical switching of thin and thick layers of dual-frequency nematics (<i>Crystals</i>, 9(6), pp. 314, 2019).