Corner Sharing Tetrahedral Network in Co<sub>3</sub>(HAT)[N(CN)<sub>2</sub>]<sub>6</sub>(OH<sub>2</sub>)<sub>2</sub> (HAT = 1,4,5,8,9,12-Hexaazatriphenylene)
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We report a trinuclear CoII complex containing bridging dicyanamides and a tris-chelated HAT, which possesses ∼37% void space. The magnetic exchange pathways appear in the structure as a corner sharing tetrahedral network. The compound crystallizes in the monoclinic space group P21/c [a = 13.655(3) Å, b = 15.189(3) Å, c = 22.367(4) Å, β = 114.100(2)°, V = 4234.5(14) Å3, Z = 4, R(Fo) = 0.0823]. The magnetic data were fit to an S = 3/2 model for systems dominated by zero-field splitting effects with g = 2.01 and D = 38.9 cm-1.
创建时间：
2016-08-17
