Gold-Catalyzed Atom-Economic Synthesis of Sulfone-Containing Pyrrolo[2,1‑<i>a</i>]isoquinolines from Diynamides: Evidence for Consecutive Sulfonyl Migration
收藏NIAID Data Ecosystem2026-03-10 收录
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资源简介：
A gold-catalyzed cascade reaction of conjugated diynamides has been developed. In this way, a series of sulfone-containing pyrrolo[2,1-a]isoquinolines featuring the core structural motifs of lamellarin alkaloids were prepared atom economically. Mechanistic studies including DFT calculations uncovered a consecutive 1,2-migration of the sulfonyl group for the formation of a pyrrole ring.
创建时间：
2019-02-20
