Unusual Open Eight-Vertex Oxamolybdaboranes: Structural Characterizations of (η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>Mo)<sub>2</sub>B<sub>5</sub>(μ<sub>3</sub>-OEt)H<sub>6</sub>R (R = H and <i>n</i>-BuO)
收藏NIAID Data Ecosystem2026-03-06 收录
数据链接：
官方服务：
资源简介：
Reaction of (η5-C5Me5)MoCl4 with a 10-fold excess of LiBH4 followed by thermolysis with excess BH3·THF in toluene led to the formation of two oxamolybdaborane clusters, (η5-C5Me5Mo)2B5(μ3-OEt)H6R (2, R = H; 3, R = n-BuO). Clusters 2 and 3 have been characterized by 1H, 11B, and 13C NMR spectra and X-ray crystal structure determinations. 2 and 3 are notable examples of oxametallaborane compounds where oxygen is contiguously bound to both the cluster metal (molybdenum) and the boron atom.
创建时间：
2016-02-26
