Palladium-Catalyzed [5 + 2] Cycloaddition of Vinyloxiranes with Sulfamate-Derived Cyclic Imines To Construct 1,3-Oxazepine Heterocycles
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下载链接:
https://figshare.com/articles/dataset/Palladium-Catalyzed_5_2_Cycloaddition_of_Vinyloxiranes_with_Sulfamate-Derived_Cyclic_Imines_To_Construct_1_3-Oxazepine_Heterocycles/5615521
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资源简介:
Palladium-catalyzed [5 + 2] cycloaddition
of 2-aryl-2-vinyloxiranes
with sulfamate-derived cyclic imines is described. The zwitterionic
allylpalladium intermediates act as five-membered synthon to react
with sulfamate-derived cyclic imines to furnish [5 + 2] cycloaddition,
giving 1,3-oxazepine derivatives in moderate to excellent yields with
excellent regioselectivities.
创建时间:
2017-11-18



