Asymmetric Total Synthesis of (−)-Aspidophylline A
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https://figshare.com/articles/dataset/Asymmetric_Total_Synthesis_of_-Aspidophylline_A/4781038
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资源简介:
An asymmetric total synthesis of (−)-aspidophylline A has been accomplished. The key transformations include an asymmetric hydride transfer hydrogenation of an α,β-acetylenic ketone and a cationic gold(I)-catalyzed 6-exo-dig cyclization involving an alkynylindole/aminal formation cascade, which enables stereoselective establishment of the requisite quaternary carbon center.
创建时间:
2017-03-23



