Nickel-Catalyzed Difunctionalization of Unactivated Alkenes Initiated by Unstabilized Enolates
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https://figshare.com/articles/dataset/Nickel-Catalyzed_Difunctionalization_of_Unactivated_Alkenes_Initiated_by_Unstabilized_Enolates/9931346
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资源简介：
This
report demonstrates the possibility of a nickel-catalyzed
difunctionalization of unactivated alkenes initiated by an unstabilized
enolate nucleophile. The process tolerates a diverse range of electrophiles,
including aryl, heteroaryl, alkenyl, and amino electrophiles. An electron-deficient
phosphine ligand and a tetrabutylammonium salt additive were crucial
for promoting efficient vicinal difunctionalization.
创建时间：
2019-09-26
