Asymmetric Intramolecular Desymmetrization of meso-α,α′-Diazido Alcohols with Aryldiazoacetates: Assembly of Chiral C3 Fragments with Three Continuous Stereocenters
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The chiral Cu-complex-catalyzed intramolecular interception of meso-α,α′-diazido alcohols with aryldiazoacetates is explored. Most of the enantioenriched α-imino esters with three continuous stereocenters are produced with good to excellent yield and enantioselectivity, and a chiral pocket model is proposed for rationalization of the asymmetric desymmetrization.
创建时间：
2016-05-02
