Ruthenium-Catalyzed Enantioselective [3+3] Cycloaddition of Propargylic Alcohols with 2-Naphthols
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https://figshare.com/articles/dataset/Ruthenium_Catalyzed_Enantioselective_3_3_Cycloaddition_of_Propargylic_Alcohols_with_2_Naphthols/2770810
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资源简介：
Ruthenium-catalyzed enantioselective [3+3] cycloaddition of propargylic alcohols with 2-naphthols affords the corresponding cycloaddition products in moderate to good yields with a high enantioselectivity (up to 99% ee). This cycloaddition proceeds via stepwise reactions of propargylation and intramolecular cyclization, where ruthenium-allenylidene and -vinylidene complexes work as reactive intermediates, respectively.
创建时间：
2010-05-10
