With Regard to the Hydrogen Bonding in Complexes of Pyridylureas, Less Is More. A Role for Shape Complementarity and CH···O Interactions?
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A pyridylurea·tetraazaanthracenedione complex with three hydrogen bonds is more stable than an analogous complex with four hydrogen bonds. An X-ray analysis and modeling suggests a steric mismatch destabilizing the latter and a CH···O contact enhancing the stability of the former.
创建时间：
2016-05-07
