One-Step Preparation and Crystallization of Almost Insoluble Palladium(II) and Platinum(II/IV) Complexes from a Biphasic Solvent System
收藏NIAID Data Ecosystem2026-03-09 收录
下载链接：
https://figshare.com/articles/dataset/One_Step_Preparation_and_Crystallization_of_Almost_Insoluble_Palladium_II_and_Platinum_II_IV_Complexes_from_a_Biphasic_Solvent_System/2113573
下载链接
链接失效反馈官方服务：
资源简介：
Scarcely soluble palladium(II) and
platinum(II/IV) halido complexes
with diamino ligands were prepared via a biphasic solvent system.
Metal precursors like tetrachloridopalladate salts were dissolved
in oxygen-free water, whereas the organic diamino ligands were dissolved
in dry and oxygen-free dichloromethane. The dichloromethane layer
was carefully covered with the aqueous layer under nitrogen atmosphere
at room temperature. The desired products crystallized within a few
weeks at the phase boundary. In the case of dihalidopalladium complexes
with diamino-binaphthalene and diamino-carbohydrate ligands, crystals
were obtained without further manipulation that were suitable for
X-ray structure analysis.
创建时间：
2016-02-12
