Heptacoordinated Molybdenum(VI) Complexes of Phenylenediamine Bis(phenolate): A Stable Molybdenum Amidophenoxide Radical
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https://figshare.com/articles/dataset/Heptacoordinated_Molybdenum_VI_Complexes_of_Phenylenediamine_Bis_phenolate_A_Stable_Molybdenum_Amidophenoxide_Radical/2413255
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资源简介：
The
syntheses, crystallographic structures, magnetic properties,
and theoretical studies of two heptacoordinated molybdenum complexes
with N,N′-bis(3,5-di-tert-butyl-2-hydroxyphenyl)-1,2-phenylenediamine (H4N2O2) are reported. A formally molybdenum(VI)
complex [Mo(N2O2)Cl2(dmf)] (1) was synthesized by the reaction between [MoO2Cl2(dmf)2] and H4N2O2, whereas the other molybdenum(VI) complex [Mo(N2O2)(HN2O2)] (2) was
formed when [MoO2(acac)2] was used as a molybdenum
source. Both complexes represent a rare case of the MoVI ion without any multiply bonded terminal ligands. In addition, molecular
structures, magnetic measurements, ESR spectroscopy, and density functional
theory calculations indicate that complex 2 is the first
stable molybdenum(VI) amidophenoxide radical.
创建时间：
2016-02-19
