Asymmetric Hydroarylation of Vinylarenes Using a Synergistic Combination of CuH and Pd Catalysis
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https://figshare.com/articles/dataset/Asymmetric_Hydroarylation_of_Vinylarenes_Using_a_Synergistic_Combination_of_CuH_and_Pd_Catalysis/3468950
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Detailed in this
Communication is the enantioselective synthesis of 1,1-diarylalkanes,
a structure found in a range of pharmaceutical drug agents and natural
products, through the employment of copper(I) hydride and palladium
catalysis. Judicious choice of ligand for both Cu and Pd enabled this
hydroarylation protocol to work for an extensive array of aryl bromides
and styrenes, including β-substituted vinylarenes and six-membered
heterocycles, under relatively mild conditions.
创建时间：
2017-06-27
