Enantiospecific Aluminum-Catalyzed (3+2) Cycloaddition of Unactivated Aziridines with Isothiocyanates
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https://figshare.com/articles/dataset/Enantiospecific_Aluminum-Catalyzed_3_2_Cycloaddition_of_Unactivated_Aziridines_with_Isothiocyanates/4037883
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资源简介:
An Al(salen)Cl efficiently catalyzed
the enantiospecific (3+2)
cycloaddition of unactivated chiral aziridines with isothiocyanates
to furnish functionalized iminothiazolidines at room temperature with
94–99% ee. The use of an aluminum Lewis acid as the catalyst,
high enantiomeric purities, mild reaction conditions, broad substrate
scope, and the high atom economy are the significant practical features.
创建时间:
2016-11-14



