Silver-Catalyzed Oxidative Cyclization of Propargylamide-Substituted Indoles: Synthesis of Phosphorated Indoloazepinones Derivatives
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https://figshare.com/articles/dataset/Silver_Catalyzed_Oxidative_Cyclization_of_Propargylamide_Substituted_Indoles_Synthesis_of_Phosphorated_Indoloazepinones_Derivatives/2087512
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资源简介：
A silver-catalyzed
oxidative cyclization of 2- or 3-propargylamide-substituted
indoles to synthesize phosphorated indoloazepinone derivatives
is described. This reaction displays a difunctionalizalion of alkynes
with diphenylphosphine oxides to construct a seven-membered
ring through a radical cyclization process. The indoloazepinones
derivatives are common structural motifs found in many natural products
and pharmaceuticals.
创建时间：
2016-02-12
