3,3‘-Oxazolidinyl-Substituted 2,2‘-Biphenyldiols: Novel Tropos Ligands with a Large Induction on the Chiral Axis
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下载链接：
https://figshare.com/articles/dataset/3_3_Oxazolidinyl_Substituted_2_2_Biphenyldiols_Novel_Tropos_Ligands_with_a_Large_Induction_on_the_Chiral_Axis/3076876
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资源简介：
A novel type of bisphenol ligand is presented which provides high modularity. Chiral information is introduced in the 3,3‘-positions as
N-arenesulfonyl-1,3-oxazolidines inducing an unexpectedly high diastereoselectivity of up to 98:2 onto the chiral axis. The impact of each part
of the molecule on the diastereomeric ratio is evaluated with extended variable-temperature (VT) NMR studies. A first example of application
in asymmetric catalysis is given.
创建时间：
2016-03-01
