Degenerate Pathways for Metallacycle Ring Inversions: A Common Phenomenon Consistent with the Principle of Microscopic Reversibility
收藏NIAID Data Ecosystem2026-03-09 收录
下载链接：
https://figshare.com/articles/dataset/Degenerate_Pathways_for_Metallacycle_Ring_Inversions_A_Common_Phenomenon_Consistent_with_the_Principle_of_Microscopic_Reversibility/2237116
下载链接
链接失效反馈官方服务：
资源简介：
Competing degenerate pathways for
ring inversion in organometallic
complexes are proposed to be ubiquitous examples that adhere to the
principle of microscopic reversibility. The NMR spectra for ring inversion
of two chromium arene dicarbonyl pyridyl chelates ([Cr{η6-C6H5(CH2)n(2-Py-κN)}(CO)2]; 2-Py =
2-pyridyl, n = 2 (1), and 3 (2)) and a manganese cyclopentadienyl dicarbonyl methyl sulfide chelate
([Mn{η5-C5H4COC(SCH3)2(SCH3-κS)}(CO)2] (3)) were characterized via variable-temperature
NMR spectroscopy and DFT theoretical calculations.
创建时间：
2016-02-16
