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[4 + 2] Annulation of Donor–Acceptor Cyclopropanes with Acetylenes Using 1,2-Zwitterionic Reactivity

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https://figshare.com/articles/dataset/_4_2_Annulation_of_Donor_Acceptor_Cyclopropanes_with_Acetylenes_Using_1_2-Zwitterionic_Reactivity/4685230
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资源简介:
A new process for the [4 + 2] annulation of donor–acceptor cyclopropanes with acetylenes under the effect of anhydrous GaCl3 using 1,2-zwitterion reactivity was elaborated. The reaction opens access to substituted dihydronaphthalenes, naphthalenes, and other fused carbocycles. The direction of the reaction can be efficiently controlled by temperature.
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2017-02-23
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