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Enhanced CO2 Binding Affinity of a High-Uptake rht-Type Metal−Organic Framework Decorated with Acylamide Groups

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Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Enhanced_CO_sub_2_sub_Binding_Affinity_of_a_High_Uptake_i_rht_i_Type_Metal_Organic_Framework_Decorated_with_Acylamide_Groups/2695546
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An rht-type metal−organic framework (MOF) prepared from M2(carboxylate)4 (M = Cu, Co) paddlewheel clusters and a flexible C3-symmetric hexacarboxylate ligand with acylamide groups exhibits larger CO2 uptake, an enhanced heat of adsorption, and higher selectivity toward CO2/N2 in comparison with what was previously observed for an analogous MOF with alkyne groups.
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2016-02-23
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