Enhanced CO2 Binding Affinity of a High-Uptake rht-Type Metal−Organic Framework Decorated with Acylamide Groups
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An rht-type metal−organic framework (MOF) prepared from M2(carboxylate)4 (M = Cu, Co) paddlewheel clusters and a flexible C3-symmetric hexacarboxylate ligand with acylamide groups exhibits larger CO2 uptake, an enhanced heat of adsorption, and higher selectivity toward CO2/N2 in comparison with what was previously observed for an analogous MOF with alkyne groups.
创建时间：
2016-02-23
