Dinuclear Oxovanadium(IV) Thiolate Complexes with Ferromagnetically Coupled Interaction between Vanadium Centers
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https://figshare.com/articles/dataset/Dinuclear_Oxovanadium_IV_Thiolate_Complexes_with_Ferromagnetically_Coupled_Interaction_between_Vanadium_Centers/2969860
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资源简介：
Two dinuclear oxovanadium(IV) thiolate complexes, [N(C5H11)4]2[VOL1]2 (1) and [N(C4H9)4][(VOL2)2(μ-OCH3)] (2) (where L1 =
[(CH3)SiO(C6H4-2-S)2]3- and L2 = [(C6H5)PO(C6H4-2-S)2]2-), have
been synthesized and characterized. The geometry of the anion
in 1 can be classified to an edge-sharing bi-square-pyramid with
a syn-orthogonal configuration. The one in 2 can be view as a
face-sharing bioctahedron with two oxo groups in syn positions.
Of note, these two complexes display intramolecular ferromagnetic
interaction between two metal centers.
创建时间：
2016-02-27
