Total Synthesis of (+)-Lepadin F
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https://figshare.com/articles/dataset/Total_Synthesis_of_Lepadin_F/2902708
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资源简介:
An enantioselective total synthesis of (+)-lepadin F is described. The synthetic sequence features an intermolecular aza-[3 + 3] annulation, homologation of a vinylogous amide via Eschenmoser’s episulfide contraction, and a highly stereoselective hydrogenation essential for achieving the 1,3-anti relative stereochemistry at C2 and C8a.
创建时间:
2008-11-06



