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An (8,3)-a 3D Coordination Network and Concomitant Three-Connected Supramolecular Isomers

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NIAID Data Ecosystem2026-03-06 收录
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An unprecedented (8,3)-a 3D coordination network was synthesized using crystal engineering strategies as one of three concomitant supramolecular isomers of the general formula [Cu2(tae)(bipy)2]·2NO3-·xS (bipy = 4,4‘-bipyridine; tae = dibasic tetraacetyl-ethane; S = solvent: H2O/MeOH). The (8,3)-a network yields optically active single crystals with 58% solvent-accessible volume, despite 4-fold interpenetration.

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2006-10-04
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