Isolation of a 2‑Hydroxytetrahydrofuran Complex from Copper-Promoted Hydroxylation of THF
收藏Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Isolation_of_a_2_Hydroxytetrahydrofuran_Complex_from_Copper_Promoted_Hydroxylation_of_THF/2391079
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资源简介：
A complex of a binucleating macrocyclic ligand comprising a [CuII(μ-OH)Na]2+ core reacts with CuI in THF/CH3CN to yield a novel species with a deprotonated 2-hydroxytetrahydrofuran (THF-2-ol) bridging between CuII and NaI ions. The complexes were characterized by X-ray crystallography, electron paramagnetic resonance spectroscopy, and electrospray ionization mass spectrometry. 18O-labeling studies support incorporation of the O atom from μ-OH into the coordinated THF-2-ol ligand.
创建时间：
2016-02-19
