Biomimetic Asymmetric Total Synthesis of (−)-Laurefucin via an Organoselenium-Mediated Intramolecular Hydroxyetherification
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https://figshare.com/articles/dataset/Biomimetic_Asymmetric_Total_Synthesis_of_Laurefucin_via_an_Organoselenium_Mediated_Intramolecular_Hydroxyetherification/2893555
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资源简介：
The first asymmetric total synthesis of (−)-laurefucin (1), a unique C-15 acetogenin with a 2,8-dioxabicyclo[5.2.1]decane skeleton, has been accomplished in nine steps in 31% overall yield from known oxocene 10. Highlights of the highly stereoselective synthesis include a novel organoselenium-mediated biomimetic hydroxyetherification.
创建时间：
2008-12-10
