Aromatic Cope Rearrangement by Gold(I) Catalysis: NMR data of pure compounds

B2FIND2026-04-11 收录

催化反应机理

磁共振表征

数据链接：

https://b2find.eudat.eu/dataset/f9ab223d-50c6-51f1-a191-3dd53cbd27d0 数据链接链接失效反馈

官方服务：

资源简介：

The Aromatic Cope Rearrangement is a highly challenging chemical reaction under thermal conditions, primarily attributed to the loss of aromaticity during the initial [3,3]...

Lewis Base Mediated β‑Elimination and Lewis Acid Mediated Insertion Reactions of Disilazido Zirconium Compounds

有机金属化学

催化反应机理

The reactivity of a series of disilazido zirconocene complexes is dominated by the migration of anionic groups (hydrogen, alkyl, halide, OTf) between the zirconium and silicon centers. The direction o

NIAID Data Ecosystem90

Allylic Amination of Pd(II)-Allyl Complexes via High-Valent Pd Intermediates

催化反应机理

烯丙基胺化反应

Organometallic high-valent Pd(allyl) complexes have been recently proposed to act as intermediates in catalytic allylic functionalization reactions. While a few PdIV(η1-allyl) complexes have been iso

NIAID Data Ecosystem50

Spectroscopic Characterization of a Monomeric, Cyclopentadienyl-Based Rhenium(V) Dioxo Complex

配合物表征

催化反应机理

Mononuclear, coordinatively unsaturated rhenium(V) dioxo species of the type XReO2 (X = Me, substituted cyclopentadienyl) have long been postulated as intermediates in rhenium-catalyzed deoxydehydrat

NIAID Data Ecosystem30

Multiple Transformations of 2‑Alkynyl-1,8-bis(dimethylamino)naphthalenes into Benzo[ g ]indoles. Pd/Cu-Dependent Switching of the Electrophilic and Nucleophilic Sites in Acetylenic Bond and a Puzzle of Porcelain Catalysis

催化反应机理

有机电环化反应

By means of Sonogashira reaction, a series of 2-alkynyl- and 2,7-dialkynyl derivatives of 1,8-bis(dimethylamino)naphthalene (“proton sponge”) have been obtained from the corresponding iodides. It w

NIAID Data Ecosystem60

Web Table 2. Free energy profile of the formation of iodotriazoles via a Cu(III) metallacycle pathway

催化反应机理

计算化学DFT

Two complementary catalytic systems are reported for the 1,3-dipolar cycloaddition of azides and iodoalkynes. These are based on two commercially available/readily available copper complexes, [CuCl(IP

NIAID Data Ecosystem40

Aromatic Cope Rearrangement by Gold(I) Catalysis: NMR data of pure compounds

资源简介：

相关数据集