Insights into Hydrogen Generation from Formic Acid Using Ruthenium Complexes
收藏NIAID Data Ecosystem2026-03-06 收录
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The decomposition of a HCO2H/Et3N azeotrope to a mixture of hydrogen and carbon dioxide may be catalyzed by a number of Ru(III) and Ru(II) complexes with high efficiency at ca. 120 °C. Evidence that suggests that the precatalyst may in each case be a common ruthenium dimer has been obtained through 1H NMR and X-ray crystallographic studies of the complexes formed in situ and of analysis of the gases generated in the reaction using FTIR and gas chromatography methods.
创建时间：
2009-07-27
