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Total Synthesis of (±)-Mersicarpine

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Figshare2008-04-03 更新2026-04-28 收录
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The first total synthesis of the indole alkaloid mersicarpine is reported. Key steps include a β-dicarbonyl radical cyclization, as well as an oxidation of the benzopyrrole moiety to establish the masked 1,2-dicarbonyl functionality. An X-ray crystal structure and discussion of the 1H NMR behavior of the natural product are also presented.

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2008-04-03
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