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Metalloporphyrinic Framework Containing Multiple Pores for Highly Efficient and Selective Epoxidation

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https://figshare.com/articles/dataset/Metalloporphyrinic_Framework_Containing_Multiple_Pores_for_Highly_Efficient_and_Selective_Epoxidation/2290837
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Metalloporphyrin MnIIICl-5,10,15,20-tetrakis­(3,5-biscarboxylphenyl)­porphyrin, having eight carboxylate groups in multiple coordination modes, connects with paddle-wheel Zn2(COO)4 units for the construction of an interesting porous porphyrinic framework that demonstrates high efficiency and stability upon epoxidation of olefins with excellent substrate size selectivity.
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2014-05-19
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