On the Reaction of 1-Oxa-4-thiaspiro[4.5]decan-7-one with PhLi. A Reinvestigation
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https://figshare.com/articles/dataset/On_the_Reaction_of_1_Oxa_4_thiaspiro_4_5_decan_7_one_with_PhLi_A_Reinvestigation/3316177
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资源简介：
Two diastereomeric alcohols are formed from the
reaction of 1-oxa-4-thiaspiro[4.5]decan-7-one with PhLi as
against the single diastereomer reported earlier. The diastereoselectivity achieved from PhMgBr is significantly
higher than with PhLi. The use of Et2O/hexane = 2:1 as the
solvent for the reaction with PhMgBr offered the highest
(14:1) diastereocontrol.
创建时间：
2016-05-06
