A Stable Vanadium(V)-Methyl Complex Containing Arylimido and Bis(ketimide) Ligands That Exhibits Unique Reactivity with Alcohol
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https://figshare.com/articles/dataset/A_Stable_Vanadium_V_Methyl_Complex_Containing_Arylimido_and_Bis_ketimide_Ligands_That_Exhibits_Unique_Reactivity_with_Alcohol/3277150
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资源简介：
An (arylimido)vanadium(V)-methyl complex
containing a ketimide ligand, (ArN)VMe(NCtBu2)2 (4,
Ar = 2,6-Me2C6H3), could be isolated and identified by
1H, 13C, and 51V NMR spectra, elemental analysis, and
X-ray crystallography. The complex 4 was treated with
alcohols (phenols), affording various methyl complexes
by ligand exchange between the ketimide and alkoxy
(aryloxo) groups exclusively, and reaction of the methyl
group with the alcohols (phenols) did not take place.
创建时间：
2016-05-05
