Synthesis, Characterization, and Structure Determination of the Heterobimetallic Polyhydride Complexes (C<sub>5</sub>Me<sub>5</sub>)Ru(<i>μ</i>-H)<sub>3</sub>MH<sub>3</sub>(C<sub>5</sub>Me<sub>5</sub>) (M = Mo, W) Containing Group VI and Group VIII Metals
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(C5Me5)Ru(μ-H)3MH3(C5Me5) (4, M = Mo; 5, M = W), the first heterobimetallic polyhydride complexes containing ruthenium and group VI metals, were synthesized, and those structures were determined by X-ray studies. The reactions of 4 and 5 with phosphines, amine, and acetylacetone were examined.
创建时间：
2016-08-26
