Asymmetric Synthesis of α‑(Diarylmethyl) Alkyl Amines through Regioselective Lithiation of α‑Diarylmethanes and the Diastereoselective Addition to Ellman’s Imines
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A highly regio- and diastereoselective lithiation/addition of α-diarylmethanes to N-tert-butanesulfinylimines is reported. This methodology also affords the preparation of enantiomerically pure α-(diarylmethyl) alkyl amines bearing quaternary centers.
创建时间：
2018-06-05
